Alumazene Reactivity with Quinolinols – Addition and Substitution Reactions on the Al3N3 Ring
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چکیده
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Synthetically versatile conjugate addition of a range of carbon, nitrogen, oxygen, sulfur and selenium nucleophiles to the highly functionalised 2-thio-3-chloroacrylamides is described. The stereochemical and synthetic features of this transformation are discussed in detail. In most instances, the nucleophile replaces the chloro substituent with retention of stereochemistry. With the oxygen nuc...
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ژورنال
عنوان ژورنال: Acta Chimica Slovenica
سال: 2018
ISSN: 1580-3155
DOI: 10.17344/acsi.2018.4624